From the Paper
"Three derivatives of cobaloximes 1 containing substituted alkyl groups linked to the cobalt atom were prepared. Cobaloximes are cobalt(III) complexes in which two dimethylgloxime anions chelate the metal and form hydrogen bonds to each other1. This results in a planar tetrahedral group surrounding the cobalt with two axial groups. One axial group is the base pyridine and the second axial group is an alkyl group. In this reaction the pH of the solution determined which derivative was prepared. The oxidative addition of the acrylonitrile ligand 2 to the reduced cobaloximes in neutral solution produced the alpha derivative. In basic solution the beta derivative was formed. The third derivative was formed with the deprotonation of the beta derivative, which then underwent oxidative addition to form the trans derivative. The spectra of the cobaloximes derivatives were recorded using infrared and 1H NMR. The spectra were in agreement with the proposed structures of the derivatives."

Tags:chelatation, cobalamins, cobaloximes

Abstract
A discussion between family members that gives a lesson in biology and defines several aspects of biology such as vegetarianism, protein, vitamin B12, cladistics, tetrapods, and antisense technology. Because this colloquial paper is written in the style of a story being told to the lay person, the reader is able to easily understand the biological concepts.

From the Paper
""I'm being more efficient," Sadie said. "The 10% rule of ecology says that only 10% of the available energy stored in a food can be used by the next level of the ecosystem. So plants can use only 10% of the energy sent by the sun, and we can use only 10% of the energy stored by plants when we eat them, or 1% of what comes from the sun. Eating meat cuts the percentage to one-tenth of 1%. Too inefficient. That's why I eat only plants" ("Vegetarianism"). Sadie nodded her head wisely.
"She's right, you know." David was a graduate student in molecular biology. He knew that sort of stuff backward and forward. Uncle Eldridge looked a little startled.
"I learned that in class, too," I added.
"But what about protein? How do you get enough protein?" Aunt Sally looked worried.
"There are a lot of sources of protein besides meat. The need for protein is based on getting both essential and non-essential amino acids from your food," Sadie explained. "It can be from complete protein foods, like meat or fish or chicken, that include all the amino acids. But non-complete protein foods are just called that because they don't include every amino acid. So you just have to combine them to get all the amino acids you need."
"Will you be able to get all your amino acids today without the turkey?" Mom asked.
"Probably," Sadie said. "The beans, the potatoes, the walnuts, and the corn in the cornbread probably include all the essential amino acids between them." ("Protein")."

Tags:dialogue, short, story, vegetarianism, protein, B12, cladistics, tetrapods, antisense